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61.
62.
《能源学会志》2019,92(4):1137-1148
Chemical looping gasification (CLG) is regarded as an innovative and promising technology for producing syngas. In this work, CLG of straw was conducted in a fixed bed reactor with Fe2O3 as the oxygen carrier, whose results led to conclusions that Fe2O3, the oxygen carrier, proved advantageous to the secondary gasification reaction and the formation of CO and CO2. It was also found that CO was further oxidized to CO2 at high Fe2O3/C molar ratio, which resulted in a decreased gasification efficiency and low heat value of syngas. Therefore, a conclusion was drawn that the most optimized Fe2O3/C molar ratio was 0.2. In addition, the alkali metals in the biomass evaporated as chlorine salts into gas phase and retained as alkali metal oxide at high temperature, resulting in coking, slagging and heating surface corrosion. In the mean time, the oxygen carrier mainly converted to Fe and sintering phenomenon was serious at high temperature despite the fact that high temperature promoted gas yield, carbon conversion efficiency and gasification efficiency. Therefore, the most optimized temperature was set to 800 °C in order to maximize gas yield and gasification efficiency. 相似文献
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64.
矿冶粉尘给一线工人皮肤健康带来严重威胁。通过添加微生物灭活芽孢于清洁皂中,研究了不同芽孢添加量对清洁皂去污能力的影响,对比了硅藻土、活性炭和芽孢添加皂在粉尘去污和重金属去除方面的异同,并通过感官评价测试了三种皂在皮肤清洁方面的效果。结果表明,添加硅藻土可以达到80%的粉尘去除率。而活性炭尽管比表面积高,但微粒细小同样易于吸附于手掌纹理中,造成二次污染,故去除率最低。在基础皂中添加1%(w/w)灭活芽孢对粉尘污染的去污率达到了95%,二次洗涤可将重金属去除率从90%提高到95%以上。感官评价中,黑色活性炭的吸附作用造成了清洗后的手掌依然不够干净,观感最差;硅藻土皂的清洁效果接近日常家用皂,观感居中;而芽孢皂的清洁效果最明显,观感最佳。 相似文献
65.
以四种不同的重油为研究对象,采用标准方法与探索实验法分别对重油密度进行测定,验证探索实验法测定重油密度的可行性。考察了油品加热时间、搅拌方式、固含量等因素对重油密度测定的影响。结果表明:在仪器准确度方面,标油不同温度时密度与给定标准值偏差均很小,试样1高温密度法与GB/T 2013—2010测定值、高温密度法20℃计算值与GB/T 13377—2010测定值偏差均很小;在实验测定影响因素方面,测定试样范围为固含量小于0.41的重质油。使用探索实验法测定重质油密度比现有国标方法更为快速,准确度及精密度更高。 相似文献
66.
Francisco Regis Machado Nascimento Aldemar Martínez González Electo Eduardo Silva Lora Albert Ratner Jose Carlos Escobar Palacio Rafaela Reinaldo 《International Journal of Hydrogen Energy》2021,46(36):18740-18766
Thermochemical conversion by gasification process is one of the most relevant technologies for energy recovery from solid fuel, with an energy conversion efficiency better than other alternatives like combustion and pyrolysis. Nevertheless, the most common technology used in the last decades for thermochemical conversion of solid fuel through gasification process, such as coal, agriculture residues or biomass residues are the fluidized bed or bubbling fluidized bed system. For these gasification technologies, an inert bed material is fed into reactor to improve the homogenization of the particles mixture and increase the heat transfer between solid fuel particles and the bed material. The fluidized bed reactors usually operate at isothermal bed temperatures in the range of 700–1000 °C, providing a suitable contact between solid and gas phases. In this way, chemical reactions with high conversion yield, as well as an intense circulation and mixing of the solid particles are encouraged. Moreover, a high gasification temperature favours carbon conversion efficiency, increasing the syngas production and energy performance of the gasifier. However, the risk of eutectic mixtures formation and its subsequent melting process are increased, and hence the probability of bed agglomeration and the system collapse could be increased, mainly when alkali and alkaline earth metals-rich biomasses are considered. Generally, bed agglomeration occurs when biomass-derived ash reacts with bed material, and the lower melting temperature of ash components promotes the formation of highly viscous layers, which encourages the progressive agglomerates creation, and consequently, the bed collapse and system de-fluidization. Taking into account the relevance of this topic to ensure the normal gasification process operating, this paper provides several aspects about bed agglomeration, mostly for biomass gasification systems. In this way, chemistry and mechanism of bed agglomeration, as well as, some methods for in-situ detection and prediction of the bed agglomeration phenomenon are reviewed and discussed. 相似文献
67.
Kai Cheng Chunchun Li Changzhi Yin Ying Tang Yihua Sun Liang Fang 《Journal of the European Ceramic Society》2019,39(13):3738-3743
The effects of Sr2+ substitution for Ba2+ on microwave dielectric properties and crystal structure of Ba3-xSrx(VO4)2 (0 ≤ x ≤ 3, BSVO) solid solution were investigated. Such Sr2+ substitution contributes to significant reduction in sintering temperature from 1400 °C to 1150 °C. Both permittivity (∑r) and quality factor (Q × f) values decreased with increasing x value, which was determined to be related with the descending values of average polarizability and packing fraction, whereas the increase in τf value was explained by the decreased average VO bond length, A-site bond valence. BSVO ceramics possessed encouraging dielectric performances with ∑r = 12.2–15.6 ± 0.1, Q × f = 44,340 - 62,000 ± 800 GHz, and τf = 24.5–64.5 ± 0.2 ppm/°C. Low-temperature sintering was manipulated by adding B2O3 as sintering additive for the representative Sr3V2O8 (SVO) ceramic and only 1 wt.% B2O3 addition successfully contributed to a 21.7% decrease in sintering temperature to 900 °C, showing good chemical compatibility with silver electrodes, which render BSVO series and SVO ceramics potential candidates in multilayer electronic devices fabrication. 相似文献
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70.
《Oil and Energy Trends》2021,46(1):29-37
Current data of world oil demand. This includes international bunkers and refinery fuel. Updated on a monthly basis. Current data of oil demand from counties such as Canada, the United States of America, Japan, OECD Europe, Belgium, France, Germany, Italy, Netherlands, Spain, Sweden, the United Kingdom, Australia, Mexico, Republic of Korea, and Turkey. Updated on a monthly basis. Current data for crude oil and refined product stocks in Canada, Chile, Mexico, the United States (Western Hemisphere), France, Germany, Italy, Netherlands, Spain, the United Kingdom and Other Europe (Europe), Japan, Republic of Korea, Other Pacific (Asia‐Pacific), and Total OECD (Table 12.1) Current data for refined product stocks in the OECD Western Hemisphere, OECD Europe, OECD Asia‐Pacific and Total OECD. Products include gasoline, diesel and gasoil, and heavy fuel oil. Updated on a monthly basis (Table 12.2). 相似文献